IRIS
TOMMASI, Immacolata Concetta
 Distribuzione geografica
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Continente #
NA - Nord America 7.629
AS - Asia 2.408
EU - Europa 2.006
SA - Sud America 505
AF - Africa 104
OC - Oceania 2
Continente sconosciuto - Info sul continente non disponibili 1
Totale 12.655
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Nazione #
US - Stati Uniti d'America 7.575
SG - Singapore 997
CN - Cina 751
SE - Svezia 450
BR - Brasile 438
DE - Germania 390
HK - Hong Kong 284
UA - Ucraina 268
RU - Federazione Russa 203
VN - Vietnam 194
GB - Regno Unito 173
FI - Finlandia 165
FR - Francia 123
IT - Italia 91
CI - Costa d'Avorio 60
IN - India 45
BE - Belgio 41
AR - Argentina 33
CA - Canada 25
NL - Olanda 23
IE - Irlanda 19
BD - Bangladesh 17
IQ - Iraq 15
MX - Messico 15
TR - Turchia 15
TN - Tunisia 13
CH - Svizzera 11
ES - Italia 11
VE - Venezuela 11
JP - Giappone 10
PK - Pakistan 10
CZ - Repubblica Ceca 9
EC - Ecuador 9
AT - Austria 8
IR - Iran 8
UZ - Uzbekistan 8
ZA - Sudafrica 8
PL - Polonia 7
SA - Arabia Saudita 7
AZ - Azerbaigian 6
ID - Indonesia 6
AM - Armenia 5
CO - Colombia 5
EE - Estonia 5
MA - Marocco 5
AE - Emirati Arabi Uniti 4
IL - Israele 4
NG - Nigeria 4
CL - Cile 3
EG - Egitto 3
LB - Libano 3
LT - Lituania 3
PA - Panama 3
PH - Filippine 3
UG - Uganda 3
BS - Bahamas 2
ET - Etiopia 2
GT - Guatemala 2
JM - Giamaica 2
MN - Mongolia 2
PE - Perù 2
SN - Senegal 2
TT - Trinidad e Tobago 2
TW - Taiwan 2
UY - Uruguay 2
AL - Albania 1
AU - Australia 1
BG - Bulgaria 1
BH - Bahrain 1
BJ - Benin 1
BO - Bolivia 1
BY - Bielorussia 1
BZ - Belize 1
DK - Danimarca 1
DO - Repubblica Dominicana 1
EU - Europa 1
GA - Gabon 1
GE - Georgia 1
JO - Giordania 1
KE - Kenya 1
KG - Kirghizistan 1
KW - Kuwait 1
LK - Sri Lanka 1
LU - Lussemburgo 1
MM - Myanmar 1
MY - Malesia 1
NI - Nicaragua 1
NO - Norvegia 1
NP - Nepal 1
NZ - Nuova Zelanda 1
OM - Oman 1
PY - Paraguay 1
QA - Qatar 1
TH - Thailandia 1
TZ - Tanzania 1
Totale 12.655
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Città #
Dallas 2.303
Jacksonville 597
Woodbridge 539
Singapore 512
Chandler 469
Ashburn 385
Fairfield 383
Houston 383
Nyköping 306
Hong Kong 278
Ann Arbor 261
Nanjing 189
Wilmington 179
Cambridge 164
Seattle 162
Beijing 132
Dong Ket 132
Munich 122
Lawrence 110
Roxbury 110
Los Angeles 97
Boardman 79
New York 77
Brooklyn 61
Abidjan 60
Des Moines 54
Nanchang 48
Porto Alegre 48
Helsinki 46
Inglewood 44
Brussels 41
Buffalo 38
São Paulo 34
Princeton 31
Hebei 30
Santa Clara 29
Shenyang 29
Tianjin 29
Jiaxing 25
San Diego 23
Guangzhou 20
North Bergen 20
Dearborn 19
Dublin 19
Ho Chi Minh City 19
Bari 18
Changsha 18
Hanoi 17
Jinan 17
Kunming 17
Moscow 17
Amsterdam 16
Paris 16
Rio de Janeiro 16
Shanghai 16
West Jordan 14
Zhengzhou 14
Belo Horizonte 13
Bologna 13
Chennai 13
London 13
Grafing 12
Atlanta 11
Washington 11
Council Bluffs 10
St Albans 10
Toronto 10
Wetter 10
Curitiba 9
San Francisco 9
Stockholm 9
Auburn Hills 8
Chicago 8
Leawood 8
Ningbo 8
Taizhou 8
Tokyo 8
Boston 7
Falkenstein 7
Malden 7
Nuremberg 7
Poplar 7
Pune 7
Redwood City 7
Tashkent 7
Ankara 6
Ardabil 6
Brno 6
Dhaka 6
Goiânia 6
Jyväskylä 6
Kansas City 6
Orem 6
Salvador 6
San Mateo 6
Vienna 6
Augusta 5
Brasília 5
Cedar Knolls 5
Denver 5
Totale 9.275
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Nome #
1,3-Dialkylimidazolium-2-carboxylates as versatile N-heterocyclic carbene–CO2 adducts employed in the synthesis of carboxylates and alpha-alkylidene cyclic carbonates 1.138
1,3-dialkylimidazolium-2-carboxylates as CO2-carriers: application in the synthesis of carboxylates, monomethylcarbonate anions and halogen free ionic liquids 1.006
1,3-Dialkylimidazolium-2-carboxylates: An entry to halogen-free ionic liquids, heterocarbenes and functionalised ionic ligands 989
“1,3-Dialkylimidazolium-2-carboxylates: Intermédiaires pour l'accès aux liquides ioniques exempts d'ions halogénure, aux hétérocarbènes et aux ligands ioniques” 220
Prospects for the Utilization of Carbon Dioxide 217
1,3-Dimethylimidazolium-2-carboxylate: the unexpected synthesis of an ionic liquid precursor and carbene-CO2 adduct 202
Enzymatic versus Chemical Carbon Dioxide Utilization. Part I. The Role of Metal Centres in Carboxylation Reactions 166
Tetraphenylborate Anion as a Phenylating Agent: Chemical and Electrochemical Reactivity of BPh4--Rh Complexes toward Mono- and Dienes and Carbon Dioxide 159
Biological Utilization of Carbon Dioxide: the Marine Biomass Option 153
Bioinorganic Chemistry of Nickel and carbon Dioxide: A Ni-Complex Behaving as a Model System for Carbon Monoxide Dehydrogenase Enzyme 153
Carbon dioxide utilisation in the chemical industry. 152
CO2-catalysed carbamation of aminofunctional silanes 150
Carbon Dioxide as Modulator of the Oxidative Properties of Dioxygen in the Presence of Transition Metal Systems 142
Carbon Dioxide as Modulator of the Oxidative Properties of Dioxygen in the Presence of Transition Metal Systems 134
Direct synthesis of ESBO derivatives-18O labelled with dioxirane 133
A technology for the treatment of olive mill waste water in a continuous fed plant 132
Reactivity of 1,3-dimethylimidazolium-2-carboxylate with dimethylcarbonate at high temperature: Unexpected 2-ethyl-functionalisation of the imidazolium moiety and employment of the NHC-CO2/dimethylcarbonate system in a base promoted reaction 124
Prospects for the Utilization of Carbon Dioxide 119
A Bonding-Reactivity Relationship for Ni(PCy3)2(CO2): A Comparative Solid-State-Solution Nuclear Magnetic Resonance Study (31P, 13C) as a Diagnostic Tool To Determine the Mode of Binding of CO2 to a Metal Center 118
Enzymatic synthesis of 4-OH-benzoic acid from phenol and CO2: the first example of a biotechnological application of a carboxylase enzyme 115
"CO2-catalyzed carbamation of aminofunctional silanes" 113
Formation of Peroxocarbonates from L3Rh(O2)Cl and L2Ni(CO2). a unique reaction mechanism with carbon dioxide insertion into the O-O bond 113
Mechanism of formation of the peroxocarbonate complex (PCy3)2Ni(CO4) from solid (PCy3)2Ni(CO2) and dioxygen: an example of solid-state metallorganic reaction involving CO2 deco-ordination and reinsertion into the O-O bond of (PCy3)2Ni(O2). Reactivity of the peroxocarbonate complex towards olefins in the solid state and in solution 111
Oxidative cleavage of lactams in water using dioxiranes; an expedient and environmentally-safe route to w-nitro acids 109
The First Synthesis of a Cyclic Carbonate from a Ketal in SC-CO2 108
Direct Carboxylation of C(sp3)-H and C(sp2)-H Bonds with CO2 by Transition-Metal-Catalyzed and Base-Mediated Reactions 108
Developing Innovative Synthetic Technologies of Industrial Relevance based on Carbon Dioxide as Raw material 106
Carboxylation and Carbonatation of Organic Substrates: Two Low Energy Ways for the Fixation of Carbon Dioxide into Organic Materials (Molecular and Polymeric) 103
Unique evidence for a Rh(III) to Rh(I) reduction by deoxygenation of a carbonate moiety to CO2 by an out-of-sphere phosphane 103
New ƒØ5- and ƒÝ-(O)-Rh(I) phenoxide complexes: synthesis, characterization and unconventional reactivity of ƒØ5-complexes towards carbon dioxide 103
Mechanism of Formation of Peroxocarbonates RhOOC(O)O(Cl)(P)3 and Their Reactivity as Oxygen Transfer Agents Mimicking Monooxygenases. The First Evidence of CO2 Insertion into the O−O Bond of Rh(η2-O2) Complexes 102
Ionic Liquids, 3. Synthesis and Utilisation of Protic Imidazolium Salts in Homogeneous Catalysis 101
Application of the impulse oscillation model for modelling the formation of peroxocarbonates via carbon dioxide reaction with dioxygen transition metal complexes. A comparison with the experimental results obtained for Rh(η2-O2)ClP3 [P = phosphane ligand] 101
Carbon dioxide utilization in chemical industry 98
Biphasic Pd-catalysed Dimerisation of methyl acrilate using an Ionic liquid catalyst layer 98
Abatement of polyphenols in industrial waste-waters: identification of new demethylating enzymes and their potential use in synthetic chemistry 97
Formation of Peroxocarbonates from L3Rh(O2)Cl and L2Ni(CO2). a unique reaction mechanism with carbon dioxide insertion into the O-O bond 97
Synthesis and utilisation of carbene carboxylates in organic synthesis 91
Complessi metallici mimetici di enzimi: riduzione del diossido di carbonio 91
Hydrogeneoimidazolium salts: bifunctional media for molecular catalysis 90
Mechanism of formation of Rh- and Ni-peroxocarbonates and their utilisation in olefin oxidation and carbonation reactions. Experimental and theoretical studies. 89
Direct synthesis of organic carbonates by oxidative carboxylation of olefins catalyzed by metal oxides: developing green chemistry based on carbon dioxide 88
Oxidative addition of allyl-ammonium and -iminium tetraphenylborates to low valent complexes. II: synthesis, cristal structure and reactivity of chiral [(3C3H5)Ni(PCy3)(NH3)]BPh4 86
Metal-Ions Dependence and Mimetic Complexes of Phenol Carboxylase: a New Enzyme Catalyzing the Carboxylation of Phenol Using CO2 86
The Role of Metal-Ions in Carboxylation- and Reduction-Reactions Utilizing Carbon Dioxide 84
Synthesis and spectroscopic characterization of Mn(II) complexes coordinating phenoxide and mono- and di-alkyl substituted phenoxide anions 84
Reduction of Co-ordinated Carbon Dioxide to Carbon Monoxide via Protonation by Thiols and Other Broensted Acids Promoted by Ni-Sistems: a Contribution to the Understanding of the Mode of Action of the Enzyme Carbon Monoxide Dehydrogenase 84
Mimetic Complexes of Phenol Carboxylase of Pseudomonas Aeruginosa: Direct Ring-carboxylation of Phenol 83
Learning from Nature : Phenol methylation promoted by a new cobalamin-dependent O-demethylating enzyme 83
Mimetic Complexes of Phenol Carboxylase of Pseudomonas Aeruginosa: Dyrect Ring-carboxylation of Phenol 82
Coordination chemistry of phenoxide ligands to Mn(II) and its relevance to the enzymatic activity of phenylphosphate carboxylase 82
Tetraphenylborate coordination chemistry and reactivity of coordinated BPh4- anion. Syntheis, characterization and properties of mono- and polynuclear Rh(h6.BPh4) complexes 82
Synthesis of 1,3-dialkylimidazolium-2-carboxylates by direct carboxylation of 1,3-dialkylimidazolium chlorides with CO2 82
Dérivés 2-carboxylates d’hétérocycle 81
Selective synthesis of 4-OH-benzoic acid from phenol and CO2 under enzymatic catalysis. 81
Imidazolium-2-carboxylates: Versatile intermediates for the synthesis of ionic liquids and ligands 80
Coordination of BPh4- Anion to Metal Centres. Synthesis and Characterization of {[(C2H4)2Rh(6-Ph)]2BPh2}O3SCF3 and {[(C2H4)2Rh(6-Ph)]3BPh}(O3SCF3)2: the First Examples of a Tetraphenylborate Anion Acting as a Twelve or Eighteen Electron Donor to Metal Centres 80
Future trends in biotechnology: The influence of transition metals in the amelioration of the quality of biogas 79
Ionic Liquids: media for better molecular catalysis 78
Na+ promoted decarboxylation of 1,3-dialkylimidazolium-2-carboxylates and their utilization in the synthesis of organic carboxylates and alkylcarbonate anions 77
Electrophilic Attack at the Carbon Dioxide Moiety in Phosphocarbamates: an Easy Way to the Synthesis of Organic Carbamates 77
Oxidative Addition of Ammonium and Iminium Tetraphenylborates to Low-Valent Metal Complexes. Evidence of Selective N-C and N-H Activation. A New, Easy Route to Cationic Allyl-and Hydrido Nickel Complexes 77
Selective Palladium-catalysed dimerisation of methyl acrylate in ionic liquids: towards a continuous process 76
Unexpected 2-ethyl-functionalisation of 1,3-dimethylimidazol-2-ylidene with dimethylcarbonate: Use of the reaction system in organocatalysis. 76
Model Compounds for Enzymes Utilizing Carbon Dioxide in the Synthesis of C1 Molecules and Carboxylates 74
Phenol Carboxylase: a New Enzyme Using CO2 in Organic Substrates Functionalisation. Metal-ions Dependence and Mimetic Complexes 74
The Role of Metal Centres in Reduction and Carboxylation Reactions Utilizing Carbon Dioxide 74
Unprecedented synthesis of 1,3-dialkylimidazolium-2-carboxylate: Applications in the synthesis of halogen-free ionic liquids and reactivity as carbon dioxide transfer agent to active C-H bonds 74
Oxidative carboxylation of olefins to afford organic carbonates: the role of metal catalysts under homogeneous and heterogeneous conditions 73
The role of metal centres in reduction and carboxylation reactions utilizing carbon dioxide 73
Reactivity of the Tetraphenylborate Anion Co-ordinated to Rh (I) 72
Thauera aromatica can utilise ferulic and veratric acids as sole source of carbon in liquid cultures and in anaerobic conditions 71
Solid state reactions implying deformation and cleavage of M-C bonds 71
Interazione di eterocumuleni con complessi di metalli di transizione. Reattività del legante fenil-8-dioxa-1,7-aza-4-fosfora(V)-8-bicicloottano(3.3.0.) in presenza di acidi di Lewis: mobilità del protone fosforanico 70
Perspectives in the Utilization of Carbon Dioxide as a Source of Carbon. A Potential Strategy for Controlling the Carbon Dioxide Emission into the Atmosphere 69
Role of Mn and Co in the anaerobic degradation of phenolic compounds by Thauera aromatica 69
Use of Impulse Oscillation Model, IOM, for modelling the reaction of Rh(I)- and Ni(0)-dioxygen complexes with carbon dioxide. Modelling the synthesis and behaviour of peroxocarbonates as mono-oxygenase-like systems towards olefins and other oxophiles 68
Solid State and Solution 13C and 31P nmr Spectroscopy for Structural Characterization of Ni(PCy3)2(CO2) 66
Synthesis and Characterization of Mono- and Polynuclear BPh4-Rh Complexes. Utilization of BPh4- as Phenylating Agent 66
Carboxylation of Hydroxyaromatic Compounds with HCO3− by Enzyme Catalysis: Recent Advances Open the Perspective for Valorization of Lignin-Derived Aromatics 66
The Role of Metal Centres in Reduction and Carboxylation Reactions Utilizing Carbon Dioxide 65
Synthesis and spectroscopic (1H NMR, ESR) characterization of new aryloxy-Mn(II) complexes: steric control over O- vs phenyl-pi-co-ordination of ArO- ligands (ArO- = C6H5O-, 4-methyl-C6H4O-, 3,5-dimethyl-C6H3O-, 2,6-di-tert-butyl-C6H3O-, 2,6-dimethyl-C6H3O-) to the "Mn(II)Cp" moiety and their reactivity with carbon dioxide 65
Hydrogeneoimidazolium salts: bifunctional media for molecular catalysis 64
Oxidative Addition of Ammonium and Iminium Tetraphenylborates to Low Valent Metal Complexes. Evidence of Selective N-C and N-H Activation 64
Utilization of Carbon Dioxide: a Strategy for the Control of its Level in the Atmosphere. The Role of the Photoconversion Technology 63
Solid State and Solution 13C and 31P nmr Spectroscopy for Structural Characterization of CO2 Metal Complexes: the Case of Ni(PCy3)2(CO2) 63
Utilization of CO2 in the Synthesis of Molecular Organic Carbonates Promoted by Metal Systems 62
Influence of iron, nickel and cobalt on biogas production during the anaerobic fermentation of FVG residual biomass 62
Exploring the reactivity of 1,3-dimethyl-2-methyleneimidazoline, an highly polarized N-heterocyclic olefin (NHO), toward Ni(II). 62
Valutazione dell'approccio LCA per la sintesi di prodotti chimici 61
null 60
Oxidative Addition of Ammonium and Iminium Tetraphenylborates to Low Valent Metal Complexes. Evidence of Selective N-C and N-H Activation. Structure and reactivity of the new cationic Ni-complexes 59
Spectroscopic Characterization of (diphos)Rh(h6-PhBPh3) in Solution and Study on its Reactivity as a Total Phenylating Agent. Formation of C-C and C-C-C Bonds by Reaction with Aldehydes 59
Small Molecules Co-ordination to Metal Centres. Utilization of Carbon Dioxide in Synthetic Chemistry 58
Prospects for the Utilisation of Carbon Dioxide 56
Oxidative Addition of Benzyliminium tetraphenylborate to Pd(dba)(dppe): Synthesis and Catalytic Activity of [(dppe)Pd(dba)η1(N)-PhCH2N=CMe2)](BPh4)2 56
Correlazione reattività-struttura di sistemi metallici biomimetici della riduzione del CO2: il caso di Ni(PCy3)2(CO2 55
Synthesis, Characterization and Reactivity of Mono- and Polynuclear BPh4-Rh Complexes. Utilization of BPh4- as Phenylating Agent 54
Utilization of CO2 in the Synthesis of Molecular Organic Carbonates Promoted by Metal Systems' 53
Reactivity of Ammonium and Iminium Tetraphenylborates towards Metal Centers in a Low Oxidation State: Evidence of Selective N-C and N-H Activation 52
Totale 12.045
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Categoria #
all - tutte 43.502
article - articoli 0
book - libri 0
conference - conferenze 0
curatela - curatele 0
other - altro 0
patent - brevetti 0
selected - selezionate 0
volume - volumi 0
Totale 43.502
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Totale Lug Ago Sett Ott Nov Dic Gen Feb Mar Apr Mag Giu
2020/2021663 0 0 0 0 0 22 112 28 134 124 67 176
2021/2022807 27 61 9 38 47 50 34 52 51 54 141 243
2022/20231.420 183 128 87 140 215 170 18 159 241 20 26 33
2023/2024565 41 81 21 103 38 97 36 22 11 29 37 49
2024/20251.902 15 41 156 105 30 141 200 182 129 69 255 579
2025/20263.889 467 502 2.087 310 355 168 0 0 0 0 0 0
Totale 12.726