Carbon dioxide co-ordinated to Ni0 is easily reduced to bound carbon monoxide by R–SH (R = H, alkyl, benzyl, phenyl, and substituted phenyl) and other Brønsted acids, providing a reasonable model for the Ni-containing enzyme carbon monoxide dehydrogenase.
Reduction of Co-ordinated Carbon Dioxide to Carbon Monoxide via Protonation by Thiols and Other Broensted Acids Promoted by Ni-Sistems: a Contribution to the Understanding of the Mode of Action of the Enzyme Carbon Monoxide Dehydrogenase
QUARANTA, Eugenio;I. Tommasi
1988-01-01
Abstract
Carbon dioxide co-ordinated to Ni0 is easily reduced to bound carbon monoxide by R–SH (R = H, alkyl, benzyl, phenyl, and substituted phenyl) and other Brønsted acids, providing a reasonable model for the Ni-containing enzyme carbon monoxide dehydrogenase.File in questo prodotto:
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