In the presence of transition metal (Fe, Rh) catalysts, CO2 can modulate the oxidative properties of O2 towards tetrahydrofuran (THF) and styrene; the intermediate formation of metal-peroxocarbonate species, [Ln[MOC(O)O-O], seems to play a key role in these processes.
Carbon Dioxide as Modulator of the Oxidative Properties of Dioxygen in the Presence of Transition Metal Systems
QUARANTA, Eugenio;I. Tommasi
1992-01-01
Abstract
In the presence of transition metal (Fe, Rh) catalysts, CO2 can modulate the oxidative properties of O2 towards tetrahydrofuran (THF) and styrene; the intermediate formation of metal-peroxocarbonate species, [Ln[MOC(O)O-O], seems to play a key role in these processes.File in questo prodotto:
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