In this paper the synthesis and characterization of tetraphenylborate transition -metal complexes are discussed. BPh4- is shown to act as a 2- to24-electron donor. Some specific features of the reactivity of tetraphenylborate anion in the presence of transition metal centers are also discussed. The ability of BPh4- to act as a "total" phenylating agent is documented.

Tetraphenylborate coordination chemistry and reactivity of coordinated BPh4- anion. Syntheis, characterization and properties of mono- and polynuclear Rh(h6.BPh4) complexes

QUARANTA, Eugenio;Tommasi I.
1997

Abstract

In this paper the synthesis and characterization of tetraphenylborate transition -metal complexes are discussed. BPh4- is shown to act as a 2- to24-electron donor. Some specific features of the reactivity of tetraphenylborate anion in the presence of transition metal centers are also discussed. The ability of BPh4- to act as a "total" phenylating agent is documented.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11586/55258
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 18
  • ???jsp.display-item.citation.isi??? 19
social impact