In this paper the synthesis and characterization of tetraphenylborate transition -metal complexes are discussed. BPh4- is shown to act as a 2- to24-electron donor. Some specific features of the reactivity of tetraphenylborate anion in the presence of transition metal centers are also discussed. The ability of BPh4- to act as a "total" phenylating agent is documented.
Tetraphenylborate coordination chemistry and reactivity of coordinated BPh4- anion. Syntheis, characterization and properties of mono- and polynuclear Rh(h6.BPh4) complexes
QUARANTA, Eugenio;Tommasi I.
1997-01-01
Abstract
In this paper the synthesis and characterization of tetraphenylborate transition -metal complexes are discussed. BPh4- is shown to act as a 2- to24-electron donor. Some specific features of the reactivity of tetraphenylborate anion in the presence of transition metal centers are also discussed. The ability of BPh4- to act as a "total" phenylating agent is documented.File in questo prodotto:
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