Cyclization of an adamantylidene-based olefin induced by aminium hexachloroantimonate salts under a nitrogen atmosphere revealed that oxidative activation by these salts may be due to SbCl6, which in combination with an oxidant counter-ion provides SbCl5 as the true reactive species. (C) 2001 Elsevier Science Ltd. All rights reserved.
Aminium hexachloroantimonate salts: a latent source of antimony pentachloride
CIMINALE, Francesco;FARINOLA, Gianluca Maria;
2001-01-01
Abstract
Cyclization of an adamantylidene-based olefin induced by aminium hexachloroantimonate salts under a nitrogen atmosphere revealed that oxidative activation by these salts may be due to SbCl6, which in combination with an oxidant counter-ion provides SbCl5 as the true reactive species. (C) 2001 Elsevier Science Ltd. All rights reserved.File in questo prodotto:
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