The catalytic system made up of cobalt(II) acetylacetonate, 2-methylpropanal and dioxygen (or air) facilitated the oxidative cleavage of (1S,2S,3R,5S)-(+)-pinanediol 1a and (1 R,2R,3S,SR)-(-)-pinanediol 1b to enantiomerically pure cis-pinonic acids 4a-b. (C) 2000 Elsevier Science B.V. All rights reserved.
Aerobic oxidative cleavage of pinanediols by cobalt(II) acetylacetonate in the presence of 2-methylpropanal
FARINOLA, Gianluca Maria;
2000-01-01
Abstract
The catalytic system made up of cobalt(II) acetylacetonate, 2-methylpropanal and dioxygen (or air) facilitated the oxidative cleavage of (1S,2S,3R,5S)-(+)-pinanediol 1a and (1 R,2R,3S,SR)-(-)-pinanediol 1b to enantiomerically pure cis-pinonic acids 4a-b. (C) 2000 Elsevier Science B.V. All rights reserved.File in questo prodotto:
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