Palladium-promoted cross-dimerization reaction of alkenylsilanes is reported for the first time, which is also one of the very first studies on oxidative cross-coupling between vinylic organometallic reagents. The reaction occurs at room temperature in aqueous micelles and represents a convenient access to alltrans pushepull butadienes.

Oxidative cross-coupling of vinylsilanes in water

FARINOLA, Gianluca Maria
2013

Abstract

Palladium-promoted cross-dimerization reaction of alkenylsilanes is reported for the first time, which is also one of the very first studies on oxidative cross-coupling between vinylic organometallic reagents. The reaction occurs at room temperature in aqueous micelles and represents a convenient access to alltrans pushepull butadienes.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11586/35060
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