Direct arylation of 5-octylthieno[3,4-c]pyrrole-4,6-dione with a series of functionalized aryl iodides via C-H bond activation is demonstrated in a deep eutectic solvent made of choline chloride and urea in non-anhydrous conditions and without exclusion of air. This is the first demonstration of a thiophene-aryl coupling via direct arylation in deep eutectic solvents.
Pd-Catalyzed Thiophene-Aryl Coupling Reaction via C-H Bond Activation in Deep Eutectic Solvents
PUNZI, Angela;COPPI, DONATO IVAN;CAPOZZI, Maria Annunziata Marcella;RAGNI, ROBERTA;BABUDRI, Francesco;FARINOLA, Gianluca Maria
2017-01-01
Abstract
Direct arylation of 5-octylthieno[3,4-c]pyrrole-4,6-dione with a series of functionalized aryl iodides via C-H bond activation is demonstrated in a deep eutectic solvent made of choline chloride and urea in non-anhydrous conditions and without exclusion of air. This is the first demonstration of a thiophene-aryl coupling via direct arylation in deep eutectic solvents.File in questo prodotto:
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farinola_ organic letters.pdf
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10.1021@acs.orglett.7b02114.pdf
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