he enantio- or diastereoselective oxidation of readily available (methylthio)methylphosphonates produces optically active (methylsulfinyl)methylphosphonates which can be used as direct precursors of chiral nonracemic methyl sulfoxides in a substitution reaction involving a carbanionic leaving group.
Enantio- or diastereoselective oxidation of (methylthio)methylphosphonates as a route to precursor of chiral sulfoxides
FRACCHIOLLA, GIUSEPPE;TORTORELLA, Paolo
1999-01-01
Abstract
he enantio- or diastereoselective oxidation of readily available (methylthio)methylphosphonates produces optically active (methylsulfinyl)methylphosphonates which can be used as direct precursors of chiral nonracemic methyl sulfoxides in a substitution reaction involving a carbanionic leaving group.File in questo prodotto:
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