The reaction of diphenyl(methoxymethyl)phosphine oxide 1 with organometallic reagents was found to lead to substitution of the methoxymethyl group. The P-phenyl substituent showed a lower propensity to undergo a displacement.
A novel carbon leaving group in the reaction of organometallic compounds with phosphine oxides
FRACCHIOLLA, GIUSEPPE;TORTORELLA, Paolo;
1999-01-01
Abstract
The reaction of diphenyl(methoxymethyl)phosphine oxide 1 with organometallic reagents was found to lead to substitution of the methoxymethyl group. The P-phenyl substituent showed a lower propensity to undergo a displacement.File in questo prodotto:
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