Trimethylbenzothiazoline 1 has been reductively lithiated by lithium 4,4'-di-t-butylbiphenylide (LDBB) leading to dianion 3, that has been trapped with electrophiles to give aminodisulfides 4, aminosulfide 8 and aminoalcohols 9.
Reductive Lithiation of a Trimethyl benzo-1,3-thiazoline: Generation of an α-Amino Tertiary Carbanion and Reactions with Electrophiles
CAPRIATI, Vito;
1995-01-01
Abstract
Trimethylbenzothiazoline 1 has been reductively lithiated by lithium 4,4'-di-t-butylbiphenylide (LDBB) leading to dianion 3, that has been trapped with electrophiles to give aminodisulfides 4, aminosulfide 8 and aminoalcohols 9.File in questo prodotto:
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