Carboxylation represents an important route to afford C-C bonds useful to make building block molecules for polymer chemistry. This chapter will focus on recent advances in the field of direct carboxylation reactions based on CO2. The use of urea and inorganic carbonate will be also discussed. Different kinds of synthetic approaches (electrochemical, photochemical, catalytic, and enzymatic) will be considered mainly as future perspectives from the point of view of possible industrial applications, focusing attention on the energy and atom economy. The use of heterogeneous catalytic species will be described, also with mechanistic considerations.
Carboxylation Reaction Based on the Direct and Indirect Uses of CO2: Sustainable Syntheses of C—CO2, O—CO2, and N—CO2Bonds
Nocito F.;Dibenedetto A.
2023-01-01
Abstract
Carboxylation represents an important route to afford C-C bonds useful to make building block molecules for polymer chemistry. This chapter will focus on recent advances in the field of direct carboxylation reactions based on CO2. The use of urea and inorganic carbonate will be also discussed. Different kinds of synthetic approaches (electrochemical, photochemical, catalytic, and enzymatic) will be considered mainly as future perspectives from the point of view of possible industrial applications, focusing attention on the energy and atom economy. The use of heterogeneous catalytic species will be described, also with mechanistic considerations.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
