The combination of hypervalent iodine (III) reagents and source of ammonia allows the genesis of iodonitrene species able to act as source of electrophilic nitrogen. Ammonia umpolung represents the net-result of this combination. Since the introduction of this method in 2016, important and unprecedented transformations have been discovered. In this short review we report the state of the art in the use of this type of iodonitrene in modern synthesis.
Hypervalent iodine (III) reagents and ammonia as useful combination for highly chemoselective N-transfer to low-valent organosulfur compounds and amines
Andresini M.Membro del Collaboration Group
;Colella M.Membro del Collaboration Group
;Degennaro L.Membro del Collaboration Group
;Luisi R.
2021-01-01
Abstract
The combination of hypervalent iodine (III) reagents and source of ammonia allows the genesis of iodonitrene species able to act as source of electrophilic nitrogen. Ammonia umpolung represents the net-result of this combination. Since the introduction of this method in 2016, important and unprecedented transformations have been discovered. In this short review we report the state of the art in the use of this type of iodonitrene in modern synthesis.File in questo prodotto:
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