Background & Objective: A green one-pot synthesis of oleic acid (1) derivatives is promoted by Rare Earth Metal (REM) triflates and commercial Molybdenum dioxo dichloride (MoCl 2 O 2 ) in the presence hydrogen peroxide as a green oxidant. Results: The protocol permits to govern the oxidation selectivity by simply choosing the proper combination of Mo and Sc catalysts. Conclusion: Methyl oleate epoxide 2a and azelaic acid 6 thus obtained are valuable industrial intermediates for synthesizing bio-compostable plastics, plasticizers of PVC, lubricating oils, cosmetics and pharmaceuticals (bactericides, anti-inflammatories, etc.).
Titolo: | Green procedure for one-pot synthesis of azelaic acid derivatives using metal catalysis |
Autori: | NACCI, Angelo [Conceptualization] |
Data di pubblicazione: | 2018 |
Rivista: | |
Handle: | http://hdl.handle.net/11586/226756 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
File | Descrizione | Tipologia | Licenza | |
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0006CHENG (1).pdf | articolo finale | Documento in Versione Editoriale | NON PUBBLICO - Accesso privato/ristretto | Open Access Visualizza/Apri |