[Figure not available: see fulltext.] A convenient synthesis of 2- and/or 3-oxazolines has been developed depending on the structure and stereochemistry of the starting amino alcohol. PhI(OAc)2acted as oxidant on the intermediate imine, as supported by NMR investigation. The findings demonstrate a new route providing access to unusual 3-oxazolines.
Use of Hypervalent Iodine in the Synthesis of Isomeric Dihydrooxazoles
Carlucci, Claudia;Tota, Arianna;Colella, Marco;Luisi, Renzo;Degennaro, Leonardo
2018-01-01
Abstract
[Figure not available: see fulltext.] A convenient synthesis of 2- and/or 3-oxazolines has been developed depending on the structure and stereochemistry of the starting amino alcohol. PhI(OAc)2acted as oxidant on the intermediate imine, as supported by NMR investigation. The findings demonstrate a new route providing access to unusual 3-oxazolines.File in questo prodotto:
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