Aziridinyllithiums 4a and 4b, which are stable at low temperature, can be generated by deprotonation of 3a and 3b. Oxazolinyl aziridines 5a-j and 6a-b have been prepared by the reaction of oxazolinyl aziridinyllithiums 4a and 4b with electrophiles. Aziridines 6c and 6d were, instead, synthesized by a Darzens-like reaction from 2-(1-chloroethyl)-2-oxazoline 1b.
Synthesis of Oxazolinyl Aziridines
CAPRIATI, Vito;
1999-01-01
Abstract
Aziridinyllithiums 4a and 4b, which are stable at low temperature, can be generated by deprotonation of 3a and 3b. Oxazolinyl aziridines 5a-j and 6a-b have been prepared by the reaction of oxazolinyl aziridinyllithiums 4a and 4b with electrophiles. Aziridines 6c and 6d were, instead, synthesized by a Darzens-like reaction from 2-(1-chloroethyl)-2-oxazoline 1b.File in questo prodotto:
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