Many reduction reactions require the use of BH3, which is commercially available as complex in many different solvents. The determination of the content of BH3 in such solutions could be an important issue when the stoichiometry of the reaction is concerned. A fast, direct, and reproducible method to establish the content of BH3 in several solutions based on 11B NMR analysis is reported.
A Practical 11B NMR Evaluation of BH3 Titer in Commercial Solutions
DE ANGELIS, SONIA;DEGENNARO, LEONARDO;LUISI, Renzo
Conceptualization
2017-01-01
Abstract
Many reduction reactions require the use of BH3, which is commercially available as complex in many different solvents. The determination of the content of BH3 in such solutions could be an important issue when the stoichiometry of the reaction is concerned. A fast, direct, and reproducible method to establish the content of BH3 in several solutions based on 11B NMR analysis is reported.File in questo prodotto:
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