A stereoselective/stereospecific synthesis of polysubstituted tetrahydronaphthols based on the Michael addition of ortho-lithiated stilbene oxides to α,β-unsaturated Fischer carbene complexes followed by an unusual cyclization of the corresponding intermediate in a 6-endo-tet mode is described.
An Efficient Route to Tetrahydronaphthols via Addition of Ortho-Lithiated Stilbene Oxides to α,β-Unsaturated Fischer Carbene Complexes
CAPRIATI, Vito;LUISI, Renzo;PERNA, FILIPPO;SALOMONE A;
2005-01-01
Abstract
A stereoselective/stereospecific synthesis of polysubstituted tetrahydronaphthols based on the Michael addition of ortho-lithiated stilbene oxides to α,β-unsaturated Fischer carbene complexes followed by an unusual cyclization of the corresponding intermediate in a 6-endo-tet mode is described.File in questo prodotto:
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