‘Gear-like’ rotations of simple CeC bonds have been observed in some aziridine methanol derivatives. These restricted rotations have been studied by dynamic and multinuclear magnetic resonance experiments, and the barrier for rotations of Csp3eCsp3 and Csp3eCsp2 bonds have been calculated. The role of an intramolecular hydrogen bond on the stereodynamics has also been demonstrated.
Restricted Rotations and Stereodynamics of Aziridine-2-Methanol Derivative
DEGENNARO, LEONARDO;LUISI, Renzo
2011-01-01
Abstract
‘Gear-like’ rotations of simple CeC bonds have been observed in some aziridine methanol derivatives. These restricted rotations have been studied by dynamic and multinuclear magnetic resonance experiments, and the barrier for rotations of Csp3eCsp3 and Csp3eCsp2 bonds have been calculated. The role of an intramolecular hydrogen bond on the stereodynamics has also been demonstrated.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
