The α-lithiation reaction of optically active oxazolinyloxiranes has been investigated. The trapping reaction with D2O, MeI and acetone affording substituted oxazolinyloxiranes proved that the corresponding lithiated species are configurationally unstable. A stereoconvergency was observed in the case of lithiation-deuteration sequence of two oxazolinyloxiranes.
Lithiation of Optically Active Oxazolinyloxiranes: Configurational Stability
LUISI, Renzo;CAPRIATI, Vito;CARLUCCI, CLAUDIA;DEGENNARO, LEONARDO;
2003-01-01
Abstract
The α-lithiation reaction of optically active oxazolinyloxiranes has been investigated. The trapping reaction with D2O, MeI and acetone affording substituted oxazolinyloxiranes proved that the corresponding lithiated species are configurationally unstable. A stereoconvergency was observed in the case of lithiation-deuteration sequence of two oxazolinyloxiranes.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
