A boronic analogue of the archetype matrix a-cyano-4-hydroxycinnamic acid (CHCA) has been synthesised providing a new ‘‘reactive matrix’’ that possesses molecular recognition properties. This matrix selectively recognizes vic-diols, a-hydroxyacids, aminols and first allowed the detection of anions as fluoride (unaffordable by usual matrices).
Boronic acid chemistry in MALDI MS: a step forward in designing a reactive matrix with molecular recognition capabilities
A. Monopoli
;CALVANO, COSIMA DAMIANA
;NACCI, Angelo;PALMISANO, Francesco
2014-01-01
Abstract
A boronic analogue of the archetype matrix a-cyano-4-hydroxycinnamic acid (CHCA) has been synthesised providing a new ‘‘reactive matrix’’ that possesses molecular recognition properties. This matrix selectively recognizes vic-diols, a-hydroxyacids, aminols and first allowed the detection of anions as fluoride (unaffordable by usual matrices).File in questo prodotto:
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