The chemistry of lithiated a-chloroalkylheterocycles such as alpha-chloroalkylbenzothiazoles, - benzotriazoles, -pyridines, -triazines, -thiazoles and -oxazolines has been reviewed. The synthetic application of this kind of chemistry for the stereoselective preparation of heteroaryl cyclopropanes, oxiranes, aziridines, alkenes and functionalised nitroarenes through a Darzens-type reaction, has been especially emphasised.
Lithiation of alpha-Chloroalkylheterocycles: Utility in Synthetic Organic Chemistry
CAPRIATI, Vito;LUISI, Renzo
2004-01-01
Abstract
The chemistry of lithiated a-chloroalkylheterocycles such as alpha-chloroalkylbenzothiazoles, - benzotriazoles, -pyridines, -triazines, -thiazoles and -oxazolines has been reviewed. The synthetic application of this kind of chemistry for the stereoselective preparation of heteroaryl cyclopropanes, oxiranes, aziridines, alkenes and functionalised nitroarenes through a Darzens-type reaction, has been especially emphasised.File in questo prodotto:
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