Novel catalytic membranes have been prepared by linking phosphotungstic acid H(3)PW(12)O(40) (W12), a polyoxometalate having interesting properties as photocatalyst, on the surface of plasma-modified membranes. Porous flat-sheet membranes made of polyvinylidene fluoride (PVDF) have been prepared by a phase-inversion technique induced by a nonsolvent. These membranes have been modified by plasma treatments on the surface to graft N-containing polar groups that are able to act as binding sites with W12 (PVDF-NH2-W12). A comparison of the surface and bulk properties of the native and modified PVDF membranes has been reported. Catalytic activity of the PVDF-NH2-W12 membranes has been evaluated in the aerobic degradation reaction of phenol in water. Catalytic tests have been carried out in a membrane reactor operating in continuous mode. Better catalytic performances have been observed for the W12 heterogenized on PVDF membrane than for W 12 in a homogeneous phase. Moreover, PVDFNH2-W12 membranes have given proof of their complete stability under photo-oxidation conditions and their good recycle. This study has shown the possibility of heterogenizing catalysts by a controlled modification of the membrane surface via a plasma technique. This new method is very versatile and can be easily extended to other catalysts. Further studies are actually in progress with other catalysts belonging to the polyoxometalates group.

Heterogenization of polyoxometalates on the surface of plasma-modified polymeric membranes

FAVIA, Pietro;
2006-01-01

Abstract

Novel catalytic membranes have been prepared by linking phosphotungstic acid H(3)PW(12)O(40) (W12), a polyoxometalate having interesting properties as photocatalyst, on the surface of plasma-modified membranes. Porous flat-sheet membranes made of polyvinylidene fluoride (PVDF) have been prepared by a phase-inversion technique induced by a nonsolvent. These membranes have been modified by plasma treatments on the surface to graft N-containing polar groups that are able to act as binding sites with W12 (PVDF-NH2-W12). A comparison of the surface and bulk properties of the native and modified PVDF membranes has been reported. Catalytic activity of the PVDF-NH2-W12 membranes has been evaluated in the aerobic degradation reaction of phenol in water. Catalytic tests have been carried out in a membrane reactor operating in continuous mode. Better catalytic performances have been observed for the W12 heterogenized on PVDF membrane than for W 12 in a homogeneous phase. Moreover, PVDFNH2-W12 membranes have given proof of their complete stability under photo-oxidation conditions and their good recycle. This study has shown the possibility of heterogenizing catalysts by a controlled modification of the membrane surface via a plasma technique. This new method is very versatile and can be easily extended to other catalysts. Further studies are actually in progress with other catalysts belonging to the polyoxometalates group.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11586/48856
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 54
  • ???jsp.display-item.citation.isi??? 53
social impact