A stereoselective/stereospecific synthesis of polysubstituted tetrahydronaphthols based on the Michael addition of ortho-lithiated stilbene oxides to α,β-unsaturated Fischer carbene complexes followed by an unusual cyclization of the corresponding intermediate in a 6-endo-tet mode is described.

An Efficient Route to Tetrahydronaphthols via Addition of Ortho-Lithiated Stilbene Oxides to α,β-Unsaturated Fischer Carbene Complexes

CAPRIATI, Vito;LUISI, Renzo;PERNA, FILIPPO;SALOMONE A;
2005-01-01

Abstract

A stereoselective/stereospecific synthesis of polysubstituted tetrahydronaphthols based on the Michael addition of ortho-lithiated stilbene oxides to α,β-unsaturated Fischer carbene complexes followed by an unusual cyclization of the corresponding intermediate in a 6-endo-tet mode is described.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11586/132881
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