This account focuses on the generation of alpha-lithiated aryloxiranes such as lithiated oxazolinylaryloxiranes, lithiated styrene-, phenylpropylene- and stilbene oxides, their chemical and configurational stability, reactivity and some synthetic applications. It is shown how these special reagents have been successfully employed for the preparation of a variety of substances including polysubstituted aryloxiranes, highly strained heterocyclic compounds, alpha,beta-epoxy-gamma-butyrolactones, cyclopropane carboxylates.
Alpha-Lithiated Aryloxiranes: Useful Reactive Intermediates
CAPRIATI, Vito;LUISI, Renzo
2005-01-01
Abstract
This account focuses on the generation of alpha-lithiated aryloxiranes such as lithiated oxazolinylaryloxiranes, lithiated styrene-, phenylpropylene- and stilbene oxides, their chemical and configurational stability, reactivity and some synthetic applications. It is shown how these special reagents have been successfully employed for the preparation of a variety of substances including polysubstituted aryloxiranes, highly strained heterocyclic compounds, alpha,beta-epoxy-gamma-butyrolactones, cyclopropane carboxylates.File in questo prodotto:
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